水质标准      水质检测       国外水质        水质文摘       水质法规       技术培训      水质论坛      认证认可

   软件下载      百科知识       友情链接        回到首页       留言本        免责声明

环境指标 :1,1,1,2-四氯乙烷

别名 1,1,1,2-Tetrachloroethane
Ethane, 1,1,1,2-tetrachloro-
分析方法 EPA Method 502.2
EPA Method 524.1
EPA Method 524.2
EPA Method 8010B
EPA Method 8021A
EPA Method 8240B
EPA Method 8260A
分子式 C2H2Cl4
用途 AS SOLVENT; MFR OF INSECTICIDES, HERBICIDES, SOIL FUMIGANTS, BLEACHES, PAINTS & VARNISHES LABORATORY REAGENT; CHEM INT FOR CHLOROCARBON SOLVENTS (NON-USA USE) 1,1,1,2-Tetrachloroethane is used as a feedstock for the production of solvents such as trichloroethylene and tetrachloroethylene
外观颜色 YELLOWISH RED
沸点 130.5 DEG C @ 760 MM HG
熔点 -70.2 DEG C
分子量 167.85
密度 1.54064 @ 20 DEG C/4 DEG C
环境影响 It does not appear that 1,1,1,2-tetrachloroethane is presently produced in the USA or is used commercially. It may, however be formed incidentally during the manufacture of other chlorinated ethanes and released into the environment as air emissions or in wastewater. If released on land, 1,1,1,2-tetrachloroethane would be expected to leach through soil and volatilize from the soil surface. If released into water, it would be primarily lost by volatilization (estimated half-life 4.2 hr from a model river). Adsorption to sediment is expected to be relatively low and bioconcentration in aquatic organisms would not be significant. 1,1,1,2-Tetrachloroethane is extremely stable in the atmosphere, reacting with photochemically produced hydroxyl radicals with an estimated half-life of 550 days. However, it will be susceptible to washout by rain. Due to its persistence, it will disperse over long distances and slowly diffuse into the stratosphere where it would be rapidly degraded.
环境降解 TERRESTRIAL FATE: If released on land, 1,1,1,2-tetrachloroethane would be expected to leach into the ground and volatilize from the soil surface. AQUATIC FATE: If released into water, 1,1,1,2-tetrachloroethane would be primarily lost by volatilization (estimated half-life 4.2 hr from a model river). Adsorption to sediment is expected to relatively low. ATMOSPHERIC FATE: 1,1,1,2-Tetrachloroethane is extremely stable in the atmosphere (estimate half-life 550 days). It will be subject to washout by rain. Due to its persistence, it will disperse over long distances and slowly diffuse into the stratosphere where it would be rapidly degraded.
饮水影响 DRINKING WATER: US Groundwater Supply Survey (945 supplies derived from groundwater chosen both randomly and on the basis that they may contain VOCs) - 1,1,1,2-tetrachloroethane was not detected in any supplies at a detection limit of 0.2 ppb . It was confirmed to be in extracts from the Carrollton water plant in New Orleans which derives its water from the Mississippi River . The concentration of 1,1,1,2-tetrachloroethane in a sample collected over 7 days was 0.11 ppb . EFFL: In a comprehensive survey of wastewater from 4000 industrial and publicly owned treatment works (POTWs) sponsored by the Effluent Guidelines Division of the U.S. EPA, 1,1,1,2-tetrachloroethane was identified in discharges of the following industrial category (frequency of occurrence, median concn in ppb): organics and plastics (1; 27.4), inorganic chemicals (4; 14.8), electronics (1; 272.6) . The highest effluent concn was 272.6 ppb in the electronics industry .